全文获取类型
收费全文 | 307篇 |
免费 | 13篇 |
国内免费 | 30篇 |
专业分类
安全科学 | 8篇 |
废物处理 | 6篇 |
环保管理 | 24篇 |
综合类 | 168篇 |
基础理论 | 11篇 |
污染及防治 | 49篇 |
评价与监测 | 83篇 |
社会与环境 | 1篇 |
出版年
2024年 | 2篇 |
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 7篇 |
2020年 | 11篇 |
2019年 | 9篇 |
2018年 | 3篇 |
2017年 | 8篇 |
2016年 | 9篇 |
2015年 | 17篇 |
2014年 | 17篇 |
2013年 | 33篇 |
2012年 | 25篇 |
2011年 | 15篇 |
2010年 | 15篇 |
2009年 | 16篇 |
2008年 | 13篇 |
2007年 | 14篇 |
2006年 | 5篇 |
2005年 | 8篇 |
2004年 | 14篇 |
2003年 | 12篇 |
2002年 | 9篇 |
2001年 | 9篇 |
2000年 | 8篇 |
1999年 | 12篇 |
1998年 | 9篇 |
1997年 | 7篇 |
1996年 | 8篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 7篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1986年 | 2篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有350条查询结果,搜索用时 36 毫秒
51.
Virus retention and transport through Al-oxide coated sand columns: effects of ionic strength and composition 总被引:11,自引:0,他引:11
Knowledge of the factors that influence the fate and transport of viruses in porous media is very important for accurately determining groundwater vulnerability and for developing protective regulations. In this study, six saturated sand column experiments were performed to examine the effects of a positively charged Al-oxide, which was coated on sand particles, on the retention and transport of viruses (phiX174 and MS-2) in background solutions of different ionic strength and composition. We found that the Al-oxide coating on sand significantly removed viruses during their transport in a phosphate buffered saline (PBS) solution. Mass balance calculations showed that 34% of the input MS-2 was inactivated/irreversibly sorbed on the surface of Al-oxide coated sand whereas 100% of phiX174 was recovered. Results from this study also indicated that higher ionic strength facilitated the transport of both phiX174 and MS-2 through the Al-oxide coated sand. This was attributed to the effect of ion shielding, which at higher ionic strength decreased the electrostatic attraction between the viral particles and the sand surface and consequently decreased virus sorption. Strong effect of the ionic strength indicates that an outer-sphere complexation mechanism was responsible for the virus sorption on the Al-oxide coated sand. Ion composition of the background solutions was also found to be a significant factor in influencing virus retention and transport. Virus transport was enhanced in the presence of phosphate (HPO(4)(2-)) as compared to bicarbonate (HCO(3)(-)), and the effect of HPO(4)(2-) was more significant on MS-2 than on phiX174. The presence of bivalent cations (Ca(2+) and Mg(2+)) increased virus transport because the cations partially screened the negative charges on the viruses therefore decreased the electrostatic attraction between the positively charged sand surface and the negatively charged viruses. Mass recovery data indicated that bivalent cations gave rise to a certain degree of inactivation/irreversibly sorption of phiX174 on the surface of Al-oxide coated sand. On the contrary, the bivalent cations appeared to have protected MS-2 from inactivation/irreversibly sorption. This study provides some insights into the mechanisms responsible for virus retention and transport in porous media. 相似文献
52.
53.
Review on the use of enzymes for the detection of organochlorine, organophosphate and carbamate pesticides in the environment 总被引:5,自引:0,他引:5
Pesticides are released intentionally into the environment and, through various processes, contaminate the environment. Three of the main classes of pesticides that pose a serious problem are organochlorines, organophosphates and carbamates. While pesticides are associated with many health effects, there is a lack of monitoring data on these contaminants. Traditional chromatographic methods are effective for the analysis of pesticides in the environment, but have limitations and prevent adequate monitoring. Enzymatic methods have been promoted for many years as an alternative method of detection of these pesticides. The main enzymes that have been utilised in this regard have been acetylcholinesterase, butyrylcholinesterase, alkaline phosphatase, organophosphorus hydrolase and tyrosinase. The enzymatic methods are based on the activation or inhibition of the enzyme by a pesticide which is proportional to the concentration of the pesticide. Research on enzymatic methods of detection, as well as some of the problems and challenges associated with these methods, is extensively discussed in this review. These methods can serve as a tool for screening large samples which can be followed up with the more traditional chromatographic methods of analysis. 相似文献
54.
Tong Li Ke Xiao Bo Yang Guilong Peng Fenglei Liu Liyan Tao Siyuan Chen Haoran Wei Gang Yu Shubo Deng 《Frontiers of Environmental Science & Engineering》2019,13(6):91
55.
The UK government has recognised the vital contribution that the construction industry has to play in contributing towards sustainable development. While the issue of hardened concrete waste has received considerable attention, process waste arising from the manufacture of ready-mixed concrete is relatively unexplored. It is apparent that initiatives such as the landfill tax have encouraged UK ready-mixed concrete manufacturers to reduce substantially the amount of waste they produce. Environmental pressures continue to increase and ready-mixed concrete producers are being forced towards a closed loop production system. 相似文献
56.
分析了人造毛皮生产中恶臭气体的来源、特点,提出了水吸收与碱吸收相结合的处理工艺。试运转结果表明, 该工艺合理,操作管理简单,具有较好的处理效果。 相似文献
57.
Phosphorus is a vital nutrient for algal growth, thus, a better understanding of phosphorus availability is essential to mitigate harmful algal blooms in lakes. Wind waves are a ubiquitous characteristic of lake ecosystems. However, its effects on the cycling of organic phosphorus and its usage by phytoplankton remain poorly elucidated in shallow eutrophic lakes. A mesocosm experiment was carried out to investigate the responses of alkaline phosphatase activity fractions to wind waves in large, shallow, eutrophic Lake Taihu. Results showed that wind-driven waves induced the release of alkaline phosphatase and phosphorus from the sediment, and dramatically enhanced phytoplanktonic alkaline phosphatase activity. However, compared to the calm conditions, bacterial and dissolved alkaline phosphatase activity decreased in wind-wave conditions. Consistently, the gene copies of Microcystis phoX increased but bacterial phoX decreased under wind-wave conditions. The ecological effects of these waves on phosphorus and phytoplankton likely accelerated the biogeochemical cycling of phosphorus and promoted phytoplankton production in Lake Taihu. This study provides an improved current understanding of phosphorus availability and the phosphorus strategies of plankton in shallow, eutrophic lakes. 相似文献
58.
采用超纯水、Na2CO3-NaHCO3NaOH3种不同的吸收液吸收爆轰气体产物、离子色谱进行样品分离、外标法定量,建立了爆轰气体产物中HF、HCl、HCN无机污染物的离子色谱分析方法。研究表明,炸药爆轰气体中合有一定量的HF、HCl和少量的HCN,选择3.2mmol/LNa2C03与1.0mmol/LNaHCO3混合溶液作为爆轰产物中无机组份的吸收液,吸收效率均值太于90%;离子色谱分析方法的相对标准偏差(RSD)小于5.0%,相关系数达到0.9990以上;进样量为100μL时,HF、HCl、HCN的检测限分别为0.04mg/m^3、0.03mg/m^3、0.05mg/m^3。该方法灵敏度高,回收率好,且样品预处理简单。 相似文献
59.
选用配备了2种不同检测器(电导检测器和直流安培检测器)的离子色谱仪对稀释后过0.22μm滤膜的水样进行分析。配备有直流安培检测器的离子色谱仪测定水中碘化物的方法在0.100~20.0μg/L范围内线性关系良好,相关系数(r)=0.9999,方法检出限为0.030μg/L,测定下限为0.120μg/L,样品加标回收率为95.0%~104%,相对标准偏差为1.06%~1.64%;配备有电导检测器的离子色谱仪测定水中碘化物的方法在20.0~2.00×105μg/L范围内线性关系良好,相关系数(r)=0.9995,方法检出限为2.00μg/L,测定下限为8.00μg/L,样品加标回收率为99.0%~110%,相对标准偏差为0.71%~3.12%。离子色谱-直流安培检测器法测定水中碘化物的方法准确度高、灵敏度高、精密度好,检出限相对较低,适用于测定ρ(碘化物)≤20.0μg/L的清洁水样;离子色谱-电导检测器法主要适用于测定ρ(碘化物)≥20.0μg/L的水样。 相似文献
60.